Introducing a pyrazole/imidazole based hybrid cyclophane: a hydrogen bond sensor and binucleating ligand precursor.
نویسندگان
چکیده
A novel cyclophane consisting of methylene-bridged imidazolium- and pyrazole-moieties (calix[4]imidazolium[2]pyrazole) and two of its applications are presented. First, supramolecular recognition of an acetonitrile molecule by hydrogen bonding in the solid state is examined. Second, the capability to act as a ligand precursor is shown by the synthesis and characterisation of the respective dinuclear NHC-nickel(II) complex.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 25 شماره
صفحات -
تاریخ انتشار 2015